Neuer Zeitschriftenbeitrag von Müller et al., 2026
Anaerobic digestion (AD) is an essential technology for renewable energy production, yet process stability and methane yield remain sensitive to various factors, particularly under high organic loading rates (OLR). This study evaluates the effects of CO2 enrichment on methane production, hydrogen concentration, oxidation-reduction potential (ORP), and pH in AD systems using food waste and maize silage as substrates. Under high OLR conditions, CO2 enrichment increased the methane yield by 6.9 % for food waste and 7.2 % for maize silage. Elevated hydrogen levels in CO2-enriched reactors are consistent with the hypothesis of altered methanogenic routing (e.g., increased relevance of hydrogenotrophic methanogenesis), which should be verified by targeted microbial and/or isotopic analyses. ORP values were consistently less negative, especially in food waste trials, where they also served as early indicators of process disturbances. No long-term pH alterations were observed. The findings highlight the potential of CO2 enrichment to enhance methane yield and improve process resilience. Monitoring CH4, H2, and ORP is essential to fully understand the underlying mechanisms and optimize AD performance under CO2-enriched conditions.
